3,365 research outputs found
Vortex images on Ba{1-x}KxFe2As2 observed directly by the magnetic force microscopy
The vortex states on optimally doped Ba0.6K0.4Fe2As2 and underdoped
Ba0.77K0.23Fe2As2 single crystals are imaged by magnetic force microscopy at
various magnetic fields below 100 Oe. Local triangular vortex clusters are
observed in optimally doped samples. The vortices are more ordered than those
in Ba(Fe{1-x}Co{x})2As2, and the calculated pinning force per unit length is
about 1 order of magnitude weaker than that in optimally Co-doped 122 at the
same magnetic field, indicating that the Co doping at the Fe sites induces
stronger pinning. The proportion of six-neighbored vortices to the total amount
increases quickly with increasing magnetic field, and the estimated value
reaches 100% at several tesla. Vortex chains are also found in some local
regions, which enhance the pinning force as well as the critical current
density. Lines of vortex chains are observed in underdoped samples, and they
may have originated from the strong pinning near the twin boundaries arising
from the structural transition.Comment: 7 pages, 8 figure
1-(2-Fluorobenzyl)quinolinium bis(2-sulfanylidene-1,3-dithiole-4,5-dithiolato-κ2 S,S′)nickelate(III)
The crystal structure of the title compound, (C16H13FN)[Ni(C3S5)2], consists of NiIII complex anions and 1-(2-fluorobenzyl)quinolinium (fbq) cations. In the complex anion, the NiIII cation is chelated by two 2-sulfanylidene-1,3-dithiole-4,5-dithiolate (dmit) dianions in a distorted square-planar geometry; the two dmit mean planes are twisted with respect to each other at a dihedral angle of 8.44 (3)°. In the fbq cation, the dihedral angle between the benzene ring and the quinoline ring system is 80.57 (14)°. The centroid–centroid distance of 3.860 (5) Å between benzene rings indicates π–π stacking between adjacent fbq cations. The distance of 3.4958 (18) Å between the S atom and the centroid of the pyridine ring suggests the existence of a lone-pair–aromatic interaction between the anion and the cation. A short S⋯S contact [3.387 (2) Å] is also observed in the crystal structure
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